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2.2 Intramolecular Forces & Potential Energy

Part of Compound Structure and Properties in AP® Chemistry. Read the opening section, then create a free account for the full interactive lesson, practice, and progress tracking.

Potential Energy vs. Distance Between Atoms

At higher distances, the atoms experience little interaction, so the potential energy is near zero. As they get closer, they attract, lowering the potential energy and reaching a minimum at the bond length. If the atoms get too close, repulsive forces push against each other, sharply increasing potential energy. Usually, the stronger the bond is the shorter its length is, so triple bonds are shorter than double bonds which are shorter than single bonds.

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