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5.7 Introduction to Reaction Mechanisms

Part of Kinetics in AP® Chemistry. Read the opening section, then create a free account for the full interactive lesson, practice, and progress tracking.

A reaction mechanism is the step-by-step sequence that shows how an overall chemical reaction actually happens. While an overall balanced equation tells you the starting substances and final products, it does not show the path the reaction follows. Many reactions do not occur in one single collision. Instead, they take place through a series of smaller elementary steps, each describing one molecular event. When all of these elementary steps are added together, they must reproduce the overall reaction.

Reaction mechanisms are important because they explain why a reaction has a certain rate law and how reactants are converted into products at the particle level. In a multistep mechanism, some substances may be formed in one step and used up in a later step. These are called intermediates. Intermediates do not appear in the final overall reaction because they cancel out when all the steps are added together. A mechanism may also include a rate-determining step, which is the slowest step and often controls the overall reaction rate.

Example 1: Suppose the overall reaction is
NO2+CO→NO+CO2NO_2 + CO \rightarrow NO + CO_2

One possible mechanism is

Step 1:
NO2+NO2→NO3+NONO_2 + NO_2 \rightarrow NO_3 + NO
Step 2:
NO3+CO→NO2+CO2NO_3 + CO \rightarrow NO_2 + CO_2
If you add the two steps together, NO_3 cancels and one NO_2 also cancels, giving the overall reaction
NO2+CO→NO+CO2NO_2 + CO \rightarrow NO + CO_2

Here, NO_3 is an intermediate.

Example 2: Suppose a reaction occurs in two steps:

Step 1:
A+B→CA + B \rightarrow C
Step 2:
C+D→EC + D \rightarrow E
The overall reaction is
A+B+D→EA + B + D \rightarrow E

The species C is produced and then consumed, so it is an intermediate and should not appear in the final overall reaction.

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