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9.1 Introduction to Entropy

Part of Thermodynamics and Electrochemistry in AP® Chemistry. Read the opening section, then create a free account for the full interactive lesson, practice, and progress tracking.

Entropy

Entropy is defined as the number of microstates that a system can have. Entropy is represented with the variable S{S} and has units of joules per mole degree kelvin. A microstate is essentially a configuration that a system can be in. Entropy is related to the amount of microstates in a system through the equation below. Note that you will not need to know this equation for the AP Exam but it is important to understand how entropy is fundamentally defined: S=kBln(W){S=k_Bln(W)}, where S{S} is the entropy of a system, kB{k_B} is the Boltzmann constant, equal to 1.38∗10−23JK{1.38*10^{-23} \frac{J}{K}}, and W{W} is the number of microstates in the system

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