Back to Thermodynamics and Electrochemistry

Lesson PreviewLesson 2 of 11 in this unit

9.2 Absolute Entropy and Entropy Change

Part of Thermodynamics and Electrochemistry in AP® Chemistry. Read the opening section, then create a free account for the full interactive lesson, practice, and progress tracking.

Absolute Entropy is simply the entropy of a system relative to if it were at absolute zero, which is defined as having no entropy. For a chemical reaction, we can find its change in entropy just like how we would find its change in enthalpy using heats of formation, by taking the sum of all the products and subtracting the sum of all reactants.
ΔSreaction∘=∑Sproducts∘−∑Sreactants∘\Delta S^\circ_{\text{reaction}} = \sum S^\circ_{\text{products}} - \sum S^\circ_{\text{reactants}}
In this case, ΔSreaction∘{\Delta S^\circ_{\text{reaction}}} is the entropy change for the reaction, ∑Sproducts∘{\sum S^\circ_{\text{products}}} is the sum of the standard entropies of the products, and ∑Sreactants∘{\sum S^\circ_{\text{reactants}}} reactants is the sum of the standard entropies of the reactants.

However, unlike heats of formation for finding enthalpy, standard entropies will always be positive, since having 0 entropy means that a solution is at absolute zero, which is physically impossible.

Continue the full lesson in Stellar

Create a free account to unlock the remaining sections, checkpoints, course practice, and progress tracking for AP® Chemistry.